Rabu, 14 November 2012

DEUTERONOMY MID SEMESTER


1                                  

         1.  pure substance x is solid at room temperature. if the substance is heated to 2300C is melted gradually. if then cooled to room temperature, the liquid can not be frozen
a.        is it possible x of an element or a compound. explain it!
b.      does it a chemical change occured? if so can it be said to undergo an endoterm changing, based on the information provided?
c.       Can it be said that the liquid is an element, based on the information provided.
Answer :

a.  X is an element of pure a.bahan for chemical elements, or simply called elements, are chemical substances that can not be subdivided into smaller substances, or can not be converted into other chemicals by using ordinary chemical methods. At room temperature (25 C) elements can be either solid, liquid, and gas.
b.  In my opinion, no chemical changes in these events because chemistry is the change undergone by an object forming a new substance. While in the event there is no new substance is produced but only changes form or physical yangdisebut with physical changes. physical changes can occur because of changes in the form and any deformities, the X is the material from solid to liquid.
      This reaction is not biased to say the reaction is endothermic because the reaction is endothermic reactions require energy or absorb energy from the environment when the reaction occurs, the reaction generally produces dingin.atau temperature endothermic reaction is a chemical reaction that absorbs heat. Heat is taken from the environment so that the enthalpy increases. in the event of such a reaction is not the case because there is no heat transfer from the system and no one called about energy or enthalpy change.
c.   Yes, because the fluid including an element or elements at room temperature (25 C) and can be solid, liquid or gas.

2.  When a candle that weight 10 gr is burned in oxygen, carbon dioxide and water vapor formed by combustion the weight more than 10 gr. Was this case match whit the law of mass. Explain it.

answer :
      I think this case is not in accordance with the law of conservation of mass because of the law of conservation of mass, also known as the Lomonosov-Lavoisier law is a law that states the mass of a closed system is constant despite the wide range of processes in the system (in a closed system mass of substances before and after the reaction is the same (fixed / constant)). Statements that are commonly used to express the law of conservation of mass is the mass can change form but can not be created or destroyed. For a chemical process in a closed system, the mass of the reactants must equal the mass of the product.
      Lavoiser have observed changes in the nature and substance he argued known as the law of conservation of mass; "In a reaction, the mass of substances before reacting equal to the mass of the substance after reacting". This suggests to us that there is no mass loss during the ongoing reaction.
      For example, if we are reacting substance A which has a mass of 10 grams with substance B (mass 10 grams) to produce substances C and D, where mass quantities of substances produced equals the number of reacting mass is 20 grams.
      Chemical reactions are written with an arrow, to the left of the arrow are substances which react and to the right of the arrows are substances the reaction.
      It is known that the mass after the reaction, is the total mass, which means that the composition of the C and D may be different from the mass of substance A and B are berkomposisi 10 grams and 10 grams. Substance C and D are formed may be 8 grams and 12 grams or 12 grams and vice versa 8 grams. The law of conservation of mass only limits on the amount of the same substance with a substance that occurs before, yet describes compounds formed.

    3.When carbon burns in oxygen under limited number, it will form two gaseous compounds. Suggest the way to differentiate the two compounds with one another.

answer :

When carbon burns under a limited amount of oxygen, it forms two gaseous compounds. These compounds are carbon monoxide.
CO (carbon monoxide) gas is highly toxic because it can bind to hemoglobin in the blood thereby blocking the main function of hemoglobin as an oxygen carrier, formed in incomplete combustion of carbon-containing fuels such as wood and gasoline, because it can burn and produce heat, then gas is used as fuel gas as the reductant in metal processing, making methanol.

carbon monoxide with H2O that forms the central atom lone pair to form a dipole moment so it is polar. based on the nature of the polarity of the molecules makes it possible to separate the pollutant gas molecules using molecular screening in accordance with the properties of impurity gas polarity.


          4.   After mendeev compiled theperiodic table, he conclude that the atomic weight of certain elements was wrong ruling, and this conclusion was apparently correct. How Mendeleev was able to predict that several atomic weight were wrong? Why his predictions are not always right. Explain!

answer :

       Dmitri Ivanovich Mendeleev in 1869 observations of 63 known elements and get the result that       properties      of elements are a periodic function of the relative atomic mass. Certain properties will be repeated periodically if unsurunsur ordered by relative atomic mass increases. The next Mendeleev placed elements with similar properties in the vertical column called class. These elements have also been prepared by the increase relative atomic mass and placed in a column called period.   
      Mendeleev deliberately emptied a few places to establish similar properties in the group. Some boxes also intentionally left blank because Mendeleev sure there's an element of the unknown because it has not been found. One element that is in line with the forecast germanium Mendeleev was previously named ekasilikon by Mendeleev.

          The weakness of this theory is still contained elements of a larger mass that lies in front of a smaller mass   elements. Co: Tellurium (te) = 128 in kiriIodin (I) = 127. this is because the elements have properties kemirpan placed in one class. The weakness of this theory is the atomic mass correction. Previous atomic mass. In previous atomic mass = 76-113. besides Be, 13.5 to 9. N 120-240.

         However, the law considers Mendeleev periodic can not tolerate any exceptions as any deviation from the order of elements by atomic weight. For example, in the case of the elements tellurium and iodine, he predicted that the atomic weights of the two elements is not appropriate because the value provided suggest the opposite order to what is determined by the chemical nature. More specifically, tellurium showed a higher atomic weight in accordance with the values ​​and subsequently measured based sequence element tellurium features will be put in the same chemical group as fluorium, klorium, and bromium, where it is not included in the periodicity of the used chemistry. Apparently, according to Mendeleev reversal sequence that is true but the reason is used inappropriately. The atomic weight is actually approaching accuracy, but the order of elements is better placed by the number of atoms of each element. Schematic sequence elements enhanced by the work of Moseley in 1912, and on the main complication lies in the mixture of isotopes occurring chemical elements are most important.
      Mendeleev periodic believes that the law can be used to predict the existence and properties of some new element compounds, as well as to correct the atomic weights of some elements are already known. However, historian and author of chemistry are emphasized in the legal aspects of prediction. Mendeleev ability to accommodate elements that are known to have contributed positively in the periodic system. For example, the quote that accompanies her awarded the Davy Medal by the Royal Society of London does not mention any of his predictions.


1                    5.    When an aqueous solution of mekuri chloride is added to an aqueous solution of silver nitrate, a white solid forms. Identify the white solid and write the balanced equation for the reaction that occurs.

         answer :

               HgCl2 +2 AgNO3 ---> Hg (NO3) 2 +2 AgCl
                the resulting white powder is silver nitrate (AgCl)














Minggu, 04 November 2012

ATOMIC STRUCTURE AND PERIODIC SYSTEM ELEMENTS


PERIODIC SYSTEM ELEMENTS

Development of the Periodic Table of Elements
Grouping elements by similar properties have evolved from the simple to the modern. The history of these developments are described in the following materials.

A. Development of Basic Grouping Elements

1. Grouping Elements Based on Metal and Non-Metal clusters are still too common as it turns out in a variety of metals and non-metallic elements are still there are many variations and the nature of the elements.

2. Law Triade Dobereiner In 1829, Johan Wolfgang Dobereiner see any resemblance between some elements of nature, and then breaks it down in terms of similar existing properties. Apparently each group consisting of three elements, the so-called Triade. If the elements are arranged according to the triade mass increases the atoms, it turns out the atomic mass and properties of the second element is the average of the atomic masses of the first and third elements.
These findings show an association between the atomic mass of the element properties. This grouping weakness lies in the fact that the number of elements with similar properties are not only 3 pieces.



3. Newlands Law of Octaves, 1864, A.R. Newlands announced the discovery of the so-called law of octaves. The elements are arranged by relative atomic mass increases. Apparently disputing elements 1 octave (element number 1 to 8, element number 2 to 9, and so on.) Shows similar properties or it could be said that the element properties change regularly. The trend is expressed as octaves Newland law, namely: If the elements arranged by atomic mass increases the properties of elements will be repeated after the eighth element.
Grouping Elements in Octave Newlands

t Newlands list compiled Octave, noble gas elements have not been
found. It turns out this is only suitable for grouping elements
light (low Ar).

4. law Mendeleyev
In 1869, the Russian scholar Dmitri Ivanovich Mendeleyev
based on observations of 63 elements known as
it concluded that the properties of elements periodic function of atomic mass
relative. That means if the elements are arranged according to the increase of mass
atom relative, certain properties will be repeated periodically.
Mendeleyev also made a list of periodic elements. The elements
which have similarities properties placed in a vertical column
called a class.
In classifying elements, Mendeleyev more emphasis
properties of the elements in the equation than the increase in mass of the atom
relative, so there are empty places in the periodic table
them. Empty places that will be filled later predicted
elements that have not been discovered at that time. At a later date the nature of prophecy
Similar corresponding predictions.
Weakness Mendeleyev Periodic Table as follows.
a. The placement of elements that do not correspond with the increase in mass of the atom
because it maintains relative similarity in the properties of elements
group.
b. There are many elements that have not been known at the time that the
there are plenty of empty tables.
Mendeleyev Periodic Table



5. Tabel Periodik Modern
Tahun 1914, Henry G. J. Moseley menemukan bahwa urutan unsur
dalam tabel periodik sesuai kenaikan nomor atom. Tabel periodik modern
yang disebut juga tabel periodik bentuk panjang, disusun menurut kenaikan
nomor atom dan kemiripan sifat. Tabel periodik modern ini dapat dikatakan
sebagai penyempurnaan Tabel Periodik Mendeleyev.
Tabel periodik bentuk panjang terdiri atas lajur vertikal (golongan) yang
disusun menurut kemiripan sifat dan lajur horizontal (periode) yang disusun
berdasarkan kenaikan nomor atomnya.
a. Lajur vertikal (golongan) ditulis dengan angka Romawi terdiri atas 18
golongan.
1) Golongan A (Golongan Utama)
Gol. IA : Alkali Gol.VA : Nitrogen
IIA : Alkali Tanah VIA : Kalkogen
IIIA : Aluminium VIIA : Halogen
IVA: Karbon VIIIA (0): Gas Mulia


PERIOD AND GROUPS IN MODERN SPU
1. Period
Is the horizontal rows of the periodic table.
Modern SPU consists of 7 periods. Each period stated amount / number of atomic shell elements that occupy those periods.
Period Number = Total Skin Atom

So:
The elements that have 1 skin (skin K only) located in period 1 (row 1), the elements of which have 2 skins (skins K and L) lies in the second period and so on.
example:
9F: 2, 7-second period
12mg: 2, 8, 2 the 3rd period
31Ga: 2, 8, 18, 3 period-4
Note:
a) Period 1, 2 and 3 is called the short period since it contains relatively few elements.
b) Period 4 and so called long period.
c) Period 7 called period is incomplete because not up to class VIII A.
d) To determine the period number of an element by atomic number, you only need to know the atomic number of the element that start each period.

2. Group
• periodic system consists of 18 vertical columns are divided into 8 main groups (group A) and 8 classes of transition (group B).
• The elements that have the same valence electrons are placed in the same group.
• For the elements of class A according to its place in the periodic system:

Group Number = Number of Valence Electrons

The elements of class A has another name, namely:
Group IA Alkali class =
Group IIA = class of Alkali Soil
Group IIIA = class of Boron
Group IVA class = Carbon
Group VA = class of Nitrogen
Group VIA = class of Oxygen
Group VIIA = class Halide / Halogen
Group VIIIA class = Noble Gases


PERIODIC PROPERTIES ELEMENTS

include:
1). Jari-Jari Atom

Is the distance from the nucleus to the electrons in the outer shell.
• The size of the atomic radius is influenced by the size of the atomic number of the element.
• The larger the atomic number of the elements of a class, the more the number of electron shell, so the larger the atomic radius.
So: in one group (from top to bottom), the atomic radius increases.
• In a period (from left to right), atomic number increases, which means the increasing nuclear charge, while the number of electrons fixed skin. As a result of the pull of the nucleus, the greater the outer electrons, resulting in increasingly smaller atomic radius.
So: in a period (from left to right), the atomic radius gets smaller.




2). Ionization Energy
Is the minimum energy required in the form of a gas of neutral atoms to release one electron to form charged ions +1.
If these atoms release electrons which the two then it would take more energy (called the second ionization energy), and so on.
EI 1 <EI 2 <EI 3 ff
In one group (from top to bottom), EI is getting smaller as the atomic radius increases, so gravity core to the outermost electron less. As a result, the outer electrons are easily released.
ΓΌ In a period (from left to right), EI greater because the atomic radius so small that gravity core to the outer electrons bigger / stronger. As a result, the outer electrons more difficult to remove.
3). Electron Affinity
• It is the energy released or absorbed by neutral atoms in gas form when receiving an electron to form negative ions.
• The price of a negative electron affinity, the easier atom receive / pull electrons and also the more reactive element.
• electron affinity is not the opposite of ionization energy.
• In one group (from top to bottom), the price of the smaller electron affinity.
• In a period (from left to right), the price of the greater electron affinity.
• main group elements have electron affinities are negative, except for groups IIA and VIIIA.
• has the largest electron affinity group VIIA.
4). electronegativity
• It is the ability of an element to attract electrons in a molecule of a compound (in bond).
• Measured using Pauling scale of between 0.7 (electronegativity Cs) to 4 (electronegativity F).
• Elements that have a large electronegativity prices, will tend to accept electrons and form negative ions.
• Elements that have small electronegativity prices, will tend to lose electrons and form positive ions.
• In one group (from top to bottom) rates, the smaller electronegativity.
• In a period (from left to right), the price of the greater electronegativity.